daniyalgreatsdk daniyalgreatsdk
  • 11-04-2021
  • Chemistry
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Would you expect polyethylene to polymerize at a faster or slower rate than polymethylmethacrylate? Explain

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GrishmaMacloen
GrishmaMacloen GrishmaMacloen
  • 11-04-2021

In radical polymerization, an acrylate forms secondary radicals as the propagating end group, while a methacrylate forms tertiary radicals (which is more stable than a secondary radical). The stability of the tertiary radical is thought to lower the reactivity of the propagating end for further polymerization.

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